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Hippokrates Ueber die Krankheiten III
irrelevant. Chemistry and the relations between science, technology, and industry are well surveyed by Crosland and Cardwell respectively. Forbes's essay on mathematical cosmography is not a comprehensive account but the story (albeit interesting) of a few German cartographers. Compared with other recent collections of essays in the history of science, this volume parades no party line: witness...
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α-Fluoro-α-nitro esters were used as reaction partners in Michael addition to nitroalkenes, and the products were obtained in excellent chemical yields and with high enantioselectivities. Moreover, α-fluoro-α-amino ester with a quaternary α-carbon was prepared for the first time.
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A Michael-type reaction of β,γ-unsaturated α-keto ester and α-nitro ketone was established. With a thiourea catalyst derived from cinchona alkaloid, the reactions afford products in 47-94% yields with 68-96% ee.
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ژورنال
عنوان ژورنال: Berichte der deutschen chemischen Gesellschaft
سال: 1889
ISSN: 0365-9496,1099-0682
DOI: 10.1002/cber.188902202138